2 edition of tert-Butylbenzene found in the catalog.
|Series||BUA Report 234|
|The Physical Object|
|Pagination||XIV, 84, 32|
Other names: Benzene, m-di-tert-butyl-; m-Di-tert-butylbenzene; 1,3-Di-tert-butylbenzene; 1,3-Ditertiarybutylbenzene; 1,3-bis(1,1-Dimethylethyl)benzene Permanent link for this species. Use this link for bookmarking this species for future reference. Information on this page: Phase change data; References; Notes; Other data available. Other names: Benzene, p-di-tert-butyl-; p-Di-tert-butylbenzene; 1,4-Di-tert-butylbenzene; Benzene, 1,4-bis-(tert-butyl) Permanent link for this species. Use this link for bookmarking this species for future reference. Information on this page: Notes; Other data available: Condensed phase thermochemistry data; Phase change data; Reaction.
Structure, properties, spectra, suppliers and links for: 1,3-Di-tert-butylbenzene, Excess molar volumes, V E, for the binary mixtures of cyclohexanone with n-, sec-, or tert-butylbenzene were measured over the entire composition range at (, , and ) K and MPa, by means of a vibrating-tube densimeter. V E data are sigmoid shape for the studied mixtures of cyclohexanone + n-butylbenzene (with negative V E values at lower Author: Dongwei Wei, Mengying Li, Jing Ma, Baohe Wang.
CAS Number Synonym(s) 1-bromotert-butylbenzene, (2-Methylpropanyl)benzene, t-butylbenzene, Benzene, (1,1-dimethylethyl)-Occurence(s)/Use(s). The acute oral LD50 value of test substance tert-Butylbenzene, for female rats, was estimated to be greater than mg kg-1 of body weight. Executive summary: In this guideline (OECD ) comparable study, the test substance tert-Butylbenzene, when administered by oral route in female rats, cause deaths, for every step taken at the dose.
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At 25 °C, a rate constant of x cm3/molecule⋅sec was reported for the gasphase reaction of tert-butylbenzene with OH radicals (Ohta and Ohyama, ).
Chemical/Physical. tert-Butylbenzene will not hydrolyze because it has no hydrolyzable functional group (Kollig, ). Chemical Name: 1,4-Di-tert-butylbenzene CAS: MDL Number: MFCD Purity: >% (GC) Molecular Formula: C14H22 Molecular Weight: Other names: Benzene, (1,1-dimethylethyl)-; tert-Butylbenzene; Dimethylethylbenzene; Phenyltrimethylmethane; Pseudobutylbenzene; Trimethylphenylmethane; 2-MethylPhenylpropane; 1,1-Dimethylethyl-benzene; t-Butylbenzene; 2-Phenylmethylpropane; Benzene, t-butyl-; NSC ; α-dimethylethylbenzene Permanent link for this species.
Use this. tert-Butylbenzene 99% Synonym: 2-Methylphenylpropane CAS Number Linear Formula C 6 H 5 C(CH 3) 3. Molecular Weight Beilstein/REAXYS Number EC Number MDL number MFCD PubChem Substance ID.
Synonym: β-Chloro-tert-butylbenzene, 1-Chloromethylphenylpropane, Neophyl chloride Linear Formula: C 6 H 5 C(CH 3) 2 CH 2 Cl Molecular Weight: Sigma-Aldrich offers a number of tert -Butylbenzene products.
View information & documentation regarding tert -Butylbenzene, including CAS, MSDS tert-Butylbenzene book more. Search results for tertbutylbenzene at Sigma-Aldrich. Compare Products: Select up to 4 products.
*Please select more than one item to compare. from cultures of achromobacter strains a2 in the presence of tert-butylbenzene, a diol was isolated and identified as 2,3-dihydro-2,3-dihydroxy-tert-butylbenzene.
evidence for meta cleavage of the aromatic ring and for accumulation of pivalic acid in the cultures was also obtained. A mixture of tert-butylbenzene and acetophenone is adsorbed onto a silica gel chromatography column and eluted with a moderately polar solvent such as dichloromethane.
Drag and drop the appropriate statements into the boxes under each named structure. Symbol which looks like a small house Solid circle with an upward pointer in it. Jump to content. 5- tert -Butylbenzene-1,3-dicarboxylic acid Article (PDF Available) in Acta Crystallographica Section E Structure Reports Online 63(9) September with.
Butylbenzene is an alkylbenzene that is benzene substituted by a butyl group at position 1. N-butylbenzene appears as a colorless liquid. Less dense than water and insoluble in water.
Used to make plastics and as a solvent. from CAMEO Chemicals. Butylbenzene belongs to the family of Substituted Benzenes. These are aromatic compounds containing. The 1,4-di-tert-butylbenzene is the result of the kinetic product control.
It crystallizes under the reaction conditions and thereby avoiding a further alkylation and isomerisation. The 1,3,5-tri-tert-butylbenzene is the thermodynamical most stable product, which can be formed from the educts.
Waste management Recycling. 1, 4-bis- (1, 1-dimethylethyl)-benzene, also known as Para-di-tert-butylbenzene, is classified as a member of the phenylpropanes. Phenylpropanes are organic compounds containing a phenylpropane moiety. 1, 4-bis- (1, 1-dimethylethyl)-benzene can be found in feces.
from Human Metabolome Database (HMDB) Expand this section. 2 Names and Identifiers. This set index page lists chemical structure articles associated with the same molecular formula. If an internal link led you here, you may wish to change the link to. Alkylation of benzene with tert-butyl chloride and aluminum chloride has been very popular in first year organic chemistry courses, but it releases HCl gas fumes.
This problem has lead to a replacement preparation using tert-butyl acetate, which Author: Jose Castrillon. The mechanism your book gives is valid because it explains how this reaction could take place along a minimal-energy pathway.
Since the reaction is observed, it somehow has to proceed from tert-butylbenzene to the products benzene and tert-butanol. I know that this is a slight tongue-in-cheeky kind of argument, but in the end it is a valid one.
N-tert-Butylbenzenesulfinimidoyl chloride is a useful oxidant for organic synthesis reactions. It is a good electrophile, and the sulfimide S=N bond can be attacked by nucleophiles, such as alkoxides, enolates, and amide ions.
The nitrogen atom in the resulting intermediate is basic, and can abstract an α-hydrogen to create a new double bondAppearance: Yellow to deep yellow-red crystals or powder. Sec-butylbenzene is an alkylbenzene that is benzene substituted by a butanyl group. Expand this section. 2 Names and Identifiers.
Expand this section. 3 Chemical and Physical Properties. Expand this section. 4 Spectral Information. Expand this section. 5 Related Records. Expand this section. 6 Chemical Vendors.
7 Pharmacology and Biochemistry. Structure, properties, spectra, suppliers and links for: t-Butylbenzene. 1,2-Di-tert-butylbenzene | C14H22 | CID - structure, chemical names, physical and chemical properties, classification, patents, literature, biological.Title Journal or Book Year; Substituent effects on the N.M.R.
spectra of carboxylic acid derivatives. III. Correlation of13C N.M.R. spectra ofparasubstituted acetanilides and 4'-nitrophenyl 4-substituted benzoates with infrared carbonyl stretching frequencies,1H N.M.R., rate and equilibrium data.n-Butylbenzene is the organic compound with the formula C 6 H 5 C 4 H two isomers of butylbenzene, n-butylbenzene consists of a phenyl group attached to the 1 position of a butyl is a slightly greasy, colorless liquid.
The synthesis of n-butylbenzene by the reaction of chlorobenzene and butylmagnesium bromide was one of the first demonstrations of the .